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You are hereHomeResearch & InnovationHIGHLIGHTS

Highlights

  • Experiments and DFT Computations Combine to Decipher Fe- Catalyzed Amidine Synthesis through Nitrene Transfer and Nitrile Insertion
    The development of multicomponent reactions (MCR) is the prefered eco-compatible approach to sophisticated molecules of pharmaceutical interest, such as amidines. We elaborated a new MCR to amidines which produces them i...
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  • Aptamer Switches Regulated by Post-Transition/Transition Metal Ions
    We have introduced an original sensing scheme that is based on the aptamer switch from a destabilized, inactive metal-complexed state to a stabilized, active target-bound conformer. The useful features of the strategy we...
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  • Optical Bacteriophage Susceptibility Screening by Surface Plasmon Resonance
    The proliferation of multiresistant bacteria is having an increasing and profound impact on the world. A credible alternative to antibiotics is bacteriophage therapy, which are expected in the near future to form the bas...
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  • Self-Assembly of a Ginkgo Oligomerization Domain Creates a Sub-10-nm Honeycomb Architecture on Carbon and Silicon Surfaces with Customizable Pores: Implications for Nanoelectronics, Biosensing, and Biocatalysis
    Surface nanopatterning with self-assembled molecules has gained in interest over the last years because of its usefullness in nanotechnology. In here, the natural abilities of a protein to self-assemble in a honeycomb st...
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  • Asymmetric Intramolecular Buchner Reaction
    Bicyclic compounds bearing a quaternary stereogenic center have been obtained using asymmetric intramolecular Buchner reaction with excellent yields and level of enantioselectivity. X-ray crystallography determination of...
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  • Efficient Electrochemical CO2/CO Interconversion by an Engineered Carbon Monoxide Dehydrogenase on a Gas-Diffusion Carbon Nanotube-Based Bioelectrode
    We have developed an enzymatic process that achieves high performance towards the reversible electrochemical CO2-to-CO conversion under mild conditions with low overvoltage. Using an engineered Carbon Monoxide Dehydrogen...
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  • Repurposing a Bio-Inspired NiFe Hydrogenase Model for CO2Reduction with Selective Production of Methane as the Unique C-Based Product
    This publication reports the unprecedented reactivity of a molecular electrocatalyst physiadsorbed on a graphite electrode: a bioinspired Ni(II)Fe(II) complex selectively and catalytically reduces CO2 in acidic aqueous s...
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  • Targeted DNP for biomolecular solid-state NM
    In targeted DNP, polarizing agents are localized at specific sites of the biomolecular system allowing the development of NMR approaches to improve sensitivity, background suppression for in-cell NMR, access to long-rang...
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  • Impact of ionomer structuration on the performance of bio-inspired noble- metal-free fuel cell anodes
    The ecological transition requires cheap and abundant electrocatalysts to achieve six key reactions: H2 evolution (HER), H2 oxidation (HOR), CO2 reduction (CO2RR), N2 reduction (NRR), O2 evolution (OER), and O2 reduction...
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  • Polysaccharides with supramolecular “glycosylations” as adaptive glycomaterials
    In collaboration between two teams of Grenoble, CERMAV & SyMMES, and a Finnish team (Aalto University – Prof. Olli IKKALA), the first ever built linear supramolecular polysaccharide has been obtained. This proof-of-con...
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